Di-tert-butylsilylene, generated by photolysis of hexa-tert-gives the corresponding alkynylsilirenes 14 and 15, respectively. Photolysis of 1 or 2 in the presence of (Me 3 Si-butylcyclotrisilane 1 or 1,1-di-tert-butyl-trans-2,3-dimethylsilirane (2), reacts with the 1,3-diyne (tBu-CฯตC-) 2 9 to CฯตC-)
โฆ LIBER โฆ
Silylene Reactions with N -Methylpyrrole: Cycloadditions and Rearrangements 1,2
โ Scribed by Weidenbruch, Manfred; Kirmaier, Lars; Marsmann, Heinrich; Jones, Peter G.
- Book ID
- 126877147
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 143 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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