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Reaction of 2,2-Bis(trifluoromethyl)-1,1-dicyanoethylene with 6,6-Dimethylfulvene: Cycloadditions and a Rearrangement

✍ Scribed by Howard, Michael H.; Alexander, Victor; Marshall, William J.; Roe, D. Christopher; Zheng, Ya-Jun


Book ID
121860311
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
311 KB
Volume
68
Category
Article
ISSN
0022-3263

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Reactions of 2-Unsubstituted 1H-Imidazol
✍ Grzegorz MlostoΕ„; Marcin JasiΕ„ski; Anthony Linden; Heinz Heimgartner πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 168 KB πŸ‘ 1 views

The reaction of 1,4,5-trisubstituted 1H-imidazole-3-oxides 1 with 2,2-bis(trifluoromethyl)ethene-1,1dicarbonitrile (7, BTF) yielded the corresponding 1,3-dihydro-2H-imidazol-2-ones 10 and 2-(1,3-dihydro-2H-imidazol-2-ylidene)malononitriles 11, respectively, depending on the solvent used. In one exam