𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Silver(I), copper(I), mercury(II) and nickel(II) hallide and perchlorate complexes with N-methylthiopyrrolidinone(2)

✍ Scribed by Peter Rechberger; Gerhard Gritzner

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
756 KB
Volume
31
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

✦ Synopsis

The synthesis, electronic absorption spectra, magnetic susceptibilities as solids and in solution, infrared spectra and conductance measurements of the following complexes with N-methylthiopyrrolidinone(2) (NMTP) are described: Ag(NMTP)&7, Ag(NMTP),Br, Ag(NMTP)I, Ag(NMTP),ClO,, Ag-(NMTP))y03, Cu(NMTP),Cl, Cu(NMTP)zBr, Cu-(NMTP),I, CU(NMTP)~C~O~, Hg(NMTP),C12, Hg-(NMTp2Br2, Hg(NMTP)212, Hg(NMTP)5(C104)2, Ni-(NMTP)2C12, Ni(NMTP))?Br2, Ni(NMTP),12 and Ni-(NMTP)4(C104)2. The nature of interaction, the coordination in the crystalline state and in solution and the dissociation of the complexes in NMTP are discussed.

πŸ“œ SIMILAR VOLUMES

Polymeric silver(I) and mercury(II) comp
Polymeric silver(I) and mercury(II) complexes with chiral bis(pyridyl) ligands
✍ Tara J. Burchell; Dana J. Eisler; Richard J. Puddephatt πŸ“‚ Article πŸ“… 2006 πŸ› Elsevier Science 🌐 English βš– 745 KB

The racemic binaphthol derivatized ligands LLZracK1,1 0 -C 20 H 12 (OCH 2 -4-C 5 H 4 N) 2 , 1, and racK1,1 0 -C 20 H 12 (OCH 2 -3-C 5 H 4 N) 2 , 2, react with silver trifluoroacetate or with mercury(II) salts to give the polymeric complexes [Ag(O 2 CCF 3 )(m-LL)] n or [HgX 2 (m-LL)] n . Individual p