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Silver(I)-catalyzed oxidation of cyclic secondary amines with peroxodisulphate

โœ Scribed by Ogawa, Keiichiro; Nomura, Yujiro; Takeuchi, Yoshito; Tomoda, Shuji

Book ID
120983633
Publisher
Royal Society of Chemistry
Year
1982
Weight
663 KB
Category
Article
ISSN
1472-7781

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๐Ÿ“œ SIMILAR VOLUMES

Oxidative decarboxylation of cyclic amin
Oxidative decarboxylation of cyclic amino acids and dehydrogenation of cyclic secondary amines with iodosobenzene
โœ Masahito Ochiai; Minako Inenaga; Yoshimitsu Nagao; Robert M. Moriarty; Radhe K V ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

## Summarv Cyclic amino acids L-proline, pipecolinic acid and L-2-pyrrolidinone-karboxylic acid undergo oxidative decarboxylation with iodosobenzene in various solvents (including water) to yield the lactam and imide in the latter case. The reaction proceeds via initial imine formation.