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Silver(I)-catalyzed oxidative cleavage reactions of cyclic 1,2-diols by peroxydisulfate

โœ Scribed by Huyser, Earl S.; Rose, Leroy G.

Book ID
125482752
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
409 KB
Volume
37
Category
Article
ISSN
0022-3263

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โœ Masao Shimizu; Hideo Orita; Kunio Suzuki; Takashi Hayakawa; Satoshi Hamakawa; Ka ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 325 KB

tic-Diols were oxidized with aqueous hydrogen peroxide in the presence of heteropolyacids to yield carboxylic acids as main products in good yields. Although the oxidation proceeded via cw-ketol or cu-diketone intermediates, another oxidation path such as direct C-C bond cleavage is suggested in the