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Silver trifluoromethanesulfonate-promoted Koenigs-Knorr reaction of Methyl 4,6-O-benzylidene-β-d-glucopyranoside with 2,3,4,6-tetra-O-acetyl-α-d-glucopyranosyl bromide

✍ Scribed by Kenc'ichi Takeo


Book ID
108308694
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
377 KB
Volume
87
Category
Article
ISSN
0008-6215

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The Koenigs-Knorr reaction of benzyl 4,6
✍ Ken'ichi Takeo; Michiaki Kitajima; Toshiya Fukatsu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 473 KB

## Note The Koenig+Knorr reaction of benzyl 4,6-O-benzylidene-fl-o-galactopyranoside with 2,3,4,6-tetra-O-acetyl-a-D-galactopyranosyl bromide In continuation of our studiesle5 on the relative reactivity ot' HO-2 and -3 in 4,6-O-benzylidene-D-glucopyranosides towards u-glucosylation 111 reactions o

Koenigs-knorr glycosidations with 3,4,6-
✍ Antonio Gómez-Sánchez; María de Gracia García-Martín; Consolación Gasch 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 729 KB

The title compound (2), readily obtained as a fairly stable, crystalline solid from 2-amino-2-deoxy-D-glucose hydrochloride through its iv-protected derivative, 2-deoxy-2-[(4,4-dimethyl-2,6-dioxocyclohexylideneme~yl)amino]-~-glucopyranose, is an excellent donor of the 2-amino-2-deoxy-&D-glucopyranos