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Silver-ion assisted reactions of chloroformate esters in benzene

โœ Scribed by Dennis N. Kevill; Werner A. Reis; Jadwiga B. Kevill

Book ID
104236518
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
212 KB
Volume
13
Category
Article
ISSN
0040-4039

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Triflate ion-promoted addition reactions
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โœ Ryohei Yamaguchi; Bunpei Hatano; Tatsuya Nakayasu; Sinpei Kozima ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 209 KB

Reaction of allyltrimethylsilane with a variety of quinolines acylated by chloroformate esters can be promoted by a catalytic amount of a triflate ion to afford 2-allyl-l,2-dihydroquinolines in good to high yields. A similar reaction with isoquinolines afforded benzoisoquinuclidine derivatives by co