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Silicon−Hydrogen Bond Activation and Formation of Silane Complexes Using a Cationic Rhodium(III) Complex

✍ Scribed by Taw, Felicia L.; Bergman, Robert G.; Brookhart, Maurice


Book ID
127067215
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
98 KB
Volume
23
Category
Article
ISSN
0276-7333

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## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),