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Silicon modified reduction and reductive alkylation-application to the phenanthrene system

✍ Scribed by Peter W. Rabideau; Zbigniew Marcinow


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
186 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


Summq A tnmethyls~yl(77MS) subshtuent 1s used to wntml the metal-ammoma reduction ofphenanthrenes

The TMS group IS then removed by tetn?bu~lammomum fluonde (TBAF) and replaced by ertber H or R '


πŸ“œ SIMILAR VOLUMES


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Methanesulfonates of saturated and unsaturated long-chain alcohols are conveniently obtained in good purity and high yields. They can be converted, quantitatively, to hydrocarbons by reduction with lithium aluminum hydride. The procedure is applicable to the preparation of alkanes and alkenes, cis,

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