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Silicon-29 chemical shifts for organosilicon reference compounds

โœ Scribed by George C Levy; J.D Cargioli; Gary E Maciel; J.J Natterstad; Earl B Whipple; M Ruta


Book ID
103187758
Publisher
Elsevier Science
Year
1973
Weight
187 KB
Volume
11
Category
Article
ISSN
0022-2364

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Deuterium isotope effects on silicon-29
โœ Fabienne Berchier; Yi-Ming Pai; William P. Weber; Kenneth L. Servis ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 291 KB

The deuterium isotope effects on the "Si chemical shifts in several organosilanes and siloxanes have been determined. For silanes, the one-bond effects are approximately -0.2ppm per deuterium and follow an additivity relationship. The two-bond effect is small.