Deuterium isotope effects on silicon-29
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Fabienne Berchier; Yi-Ming Pai; William P. Weber; Kenneth L. Servis
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Article
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1986
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John Wiley and Sons
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English
โ 291 KB
The deuterium isotope effects on the "Si chemical shifts in several organosilanes and siloxanes have been determined. For silanes, the one-bond effects are approximately -0.2ppm per deuterium and follow an additivity relationship. The two-bond effect is small.