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Silica-Supported, Single-Site Titanium Catalysts for Olefin Epoxidation. A Molecular Precursor Strategy for Control of Catalyst Structure

✍ Scribed by Jarupatrakorn, Jonggol; Tilley, T. Don


Book ID
118066702
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
122 KB
Volume
124
Category
Article
ISSN
0002-7863

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A series of Zr based catalysts were synthesized using tetraneopentylzirconium as precursor complex and a silica partially dehydroxylated. Modifications of the Zr coordination sphere of the anchored complex, (=SiO)ZrNp, (Np = neopentyl), by hydrolysis or hydrogenolysis lead to catalysts showing unexp