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Significant Conformational Changes Associated with Molecular Transport in a Crystalline Solid

✍ Scribed by Martí-Rujas, Javier; Harris, Kenneth D. M.; Desmedt, Arnaud; Guillaume, François


Book ID
127290974
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
265 KB
Volume
110
Category
Article
ISSN
0022-3654

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The dimeric Rh(I) complex, Rh,(PNP)$+ (where PNP= CH,N [ P(OCH,),],). adopts a flexible "basket" type structure. The solid state phosphorescence from the (C6H&B-salts of the dimeric complex (two crystallographic forms) indicates a thermally activated conformational change in the triplet excited stat