Significance of Intermolecular S···C(π) Interaction Involving M–S and –C=O Centers in Crystal Structures of Metal Thiolate Complexes
✍ Scribed by Janusz Lewiński; Wojciech Bury; Iwona Justyniak
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 124 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
Rotational barriers and π conjugation effects have been SCH 3 species. An acute B-S-C angle (69.6°) is found, thus evidencing a direct H•••B agostic interaction with a four-studied in H 2 X-YR systems (X = Al, B; Y = O, S; R = H, CH 3 ) by means of ab initio calculations at the MP4/6-311G\*\*// memb
## Abstract The complex [IrCl~3~(CO)(**1**)](**4,1**=2,11‐bis (diphenylphosphinomethyl)benzo[__c__]phenanthrene) has been prepared by CuCl~2~‐oxidation of [IrCl(CO)(**1**)](**2a**). It is shown that the chlorine oxidation of **2a** gives a mixture of products whose composition depends on the reacti