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.sigma. and .pi. Effects on the copper(II)/copper(I) redox couple potential in tetraazamacrocyclic complexes

✍ Scribed by Fabbrizzi, Luigi.; Lari, Annalisa.; Poggi, Antonio.; Seghi, Barbara.


Book ID
126975963
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
435 KB
Volume
21
Category
Article
ISSN
0020-1669

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Substituent effect on the redox potentia
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meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction