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Copper(II) complexes of symmetric and asymmetric bis(imine) ligands: Tuning the Cu(I)/Cu(II) redox couple

✍ Scribed by Jozwiuk, Anna; Wang, Zhaodong; Powell, Douglas R.; Houser, Robert P.


Book ID
123531373
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
483 KB
Volume
394
Category
Article
ISSN
0020-1693

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## Abstract The complexation of Cu(I) and Cu(II) by a series of 12‐, 14‐ and 16‐membered macrocyclic ligands **1–6** containing the N~2~S~2~ donor set has been studied potentiometrically, spectrophotometrically and voltammetrically. In the case of Cu(II), mononuclear complexes CuL^2+^ with stabili