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Shuttle Mechanism for Charge Transfer in Coulomb Blockade Nanostructures

โœ Scribed by Gorelik, L. Y.; Isacsson, A.; Voinova, M. V.; Kasemo, B.; Shekhter, R. I.; Jonson, M.

Book ID
121318224
Publisher
The American Physical Society
Year
1998
Tongue
English
Weight
267 KB
Volume
80
Category
Article
ISSN
0031-9007

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Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.