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Shortcomings of Basing Radical Stabilization Energies on Bond Dissociation Energies of Alkyl Groups to Hydrogen

✍ Scribed by Zavitsas, Andreas A.; Rogers, Donald W.; Matsunaga, Nikita

Book ID: 127374680
Publisher: American Chemical Society
Year: 2010
Tongue: English
Weight: 677 KB
Volume: 75
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo101127m

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## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie