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Determination of enthalpies of formation of organic free radicals based on bond dissociation energies. 4. Alkyl-substituted derivatives of phenyl and benzyl

✍ Scribed by Yu. D. Orlov; V. O. Lavrov; Yu. A. Lebedev

Book ID
110301073
Publisher
Springer
Year
2001
Tongue
English
Weight
284 KB
Volume
50
Category
Article
ISSN
1573-9171

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## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie