Short time semiclassical dynamics of optical processes in condensed phases
β Scribed by Lowell W. Ungar; Jeffrey A. Cina
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 455 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-2313
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π SIMILAR VOLUMES
A semiclassical surface-hopping propagator for problems involving nonadiabatic transitions is discussed. The propagator is employed in expressions for the probability of transitions between quantum states of molecules in condensed phases. This approach is implemented for the evaluation of the rate o
## Abstract | ββI. | Introduction | 00 | | βII. | OffβLine Sampling | 00 | | | A.ββQuantitative Approaches for Kinetics Determinations | 00 | | | B.ββCharacterization of Intermediates in Chemical Reactions | 00 | | | C.ββOffβLine Investigation of Catalysis in Biological Systems | 00 | | III. | C
Picosecond time-resolved mulnphoton ionization has brcn esrcnded IO studies of photochemical d) rumics m the condenscd phase. The early time dynamics of phenyl-substituted ethylenes reflect the loss of S, -'3,~ rcson~ntly snhan'rd ionization due to conformational motion along the isomcrization coord