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Short and Stereoselective Synthesis of C-Glycosylated Glycine Derivatives from Glycals by Radical Addition and Reduction.

โœ Scribed by Thomas Sommermann; Boo Geun Kim; Karl Peters; Eva-Maria Peters; Torsten Linker


Publisher
John Wiley and Sons
Year
2005
Weight
25 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes. -Photolysis (or thermolysis) of telluroglycosides [cf. (I)] generates glycosyl radicals which react with terminal alkynes (II) to provide anomeric mixtures of