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ChemInform Abstract: Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes.

✍ Scribed by Shigeru Yamago; Hiroshi Miyazoe; Jun-ichi Yoshida

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199925188

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✦ Synopsis

Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes.

-Photolysis (or thermolysis) of telluroglycosides [cf. (I)] generates glycosyl radicals which react with terminal alkynes (II) to provide anomeric mixtures of vinylic C-glycosides (III) and (IV). -(YAMAGO,

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