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ChemInform Abstract: Reversible Generation of Glycosyl Radicals from Telluroglycosides under Photochemical and Thermal Conditions.

โœ Scribed by Shigeru Yamago; Hiroshi Miyazoe; Jun-ichi Yoshida

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Vinyli
ChemInform Abstract: Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes.
โœ Shigeru Yamago; Hiroshi Miyazoe; Jun-ichi Yoshida ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB

Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes. -Photolysis (or thermolysis) of telluroglycosides [cf. (I)] generates glycosyl radicals which react with terminal alkynes (II) to provide anomeric mixtures of