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Shock wave study of the thermal dissociation of CF3NO

✍ Scribed by K. Glänzer; M. Maier; J. Troe


Book ID
107732131
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
347 KB
Volume
61
Category
Article
ISSN
0009-2614

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Shock wave study of the UV spectrum of C
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The UV absorption spectrum and the dissociation rate of CF$ in Ar have been measured in shock waves. For [Ar] = 1.7 X 10m5 mol cmW3, the dissociation rate constant k/[Ar] = 1.5 x 1016 exp(-168 kJ moi-'/RT) cm? mol -l s-l\_ The absorption cross section 0 = aF" [tgh(ee/ZT)] 8, = 409 K, A"o = 2370 cm-l

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The kinetics of the reaction of CF,CFHO, radicals with NO was studied by flash photolysis-time-resolved mass spectrometry. From the kinetic growth rate of NO: molecular ions the rate coefficient of the reaction CF,CFHO, + NO -+ CF,CFHO + NO, was determined to be k = (1.31 &-0.30) X 10-l' cm3 molecul