Shock wave study of the thermal dissociation of CF3NO
✍ Scribed by K. Glänzer; M. Maier; J. Troe
- Book ID
- 107732131
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 347 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The UV absorption spectrum and the dissociation rate of CF$ in Ar have been measured in shock waves. For [Ar] = 1.7 X 10m5 mol cmW3, the dissociation rate constant k/[Ar] = 1.5 x 1016 exp(-168 kJ moi-'/RT) cm? mol -l s-l\_ The absorption cross section 0 = aF" [tgh(ee/ZT)] 8, = 409 K, A"o = 2370 cm-l
The kinetics of the reaction of CF,CFHO, radicals with NO was studied by flash photolysis-time-resolved mass spectrometry. From the kinetic growth rate of NO: molecular ions the rate coefficient of the reaction CF,CFHO, + NO -+ CF,CFHO + NO, was determined to be k = (1.31 &-0.30) X 10-l' cm3 molecul