Shock Tube Kinetic Study for the Reaction of H Atoms with SO 2 : Comparison between Experiments and Theory
โ Scribed by Murakami, Yoshinori; Onishi, Shouichi; Fujii, Nobuyuki
- Book ID
- 126201750
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 61 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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The reaction of H atoms with SiCl 4 was studied behind reflected shock waves at temperatures between 1530 K and 1730 K and pressures around 1.5 bar by applying atomic resonance absorption spectroscopy (ARAS) for time resolved measurements of H atoms at the L โฃ -line. The thermal decomposition of a f
## Abstract The rate coefficient for NH~2~ + CH~4~ โ NH~3~ + CH~3~ (R1) has been measured in a shock tube in the temperature range 1591โ2084 K using FM spectroscopy to monitor NH~2~ radicals. The measurements are combined with a calculation of the potential energy surface and canonical transition s