Shifting Paradigms: Electrostatic Interactions and Covalent Bonding
β Scribed by Heiko Jacobsen
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 351 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0947-6539
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π SIMILAR VOLUMES
In the present work, a theoretical analysis was carried out on the effect of the proximity of a polar bond to a polarizable bond on the magnetic shielding constants of the nuclei belonging to the polarizable bond. In particular, the case of 13 C magnetic shielding constants in a vinylic C C bond is
## Abstract Review: 205 refs.
The recently proposed empirical analysis of 8and y-SCS in terms of the local non-bonded van der Waals and electrostatic intramolecular interaction energies is extended to an application for the "C NMR chemical shifts (6) of primary, secondary and tertiary carbon atoms of numerous classes of unsubsti
## Abstract The electrostatic properties of halogen atoms are studied theoretically in relation to their ability of halogen bonding, which is an attractive intermolecular interaction of a covalently bonded halogen atom with a negatively charged atom of a neighboring molecule. The electric quadrupol