## Abstract The sensitivity that can be obtained with the quadrupole ion trap for on‐line CE analysis using a sheathless electrospray interface and gold‐tipped columns is examined. Capillaries of different i.d. are compared in continuous infusion experiments and the effects of sheath solvents on th
✦ LIBER ✦
Sheathless electrospray ionization interfaces for capillary electrophoresis–mass spectrometric detection: Advantages and limitations
✍ Scribed by Haleem J. Issaq; George M. Janini; King C. Chan; Timothy D. Veenstra
- Book ID
- 108094212
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 205 KB
- Volume
- 1053
- Category
- Article
- ISSN
- 1873-3778
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Two previously unreported sources of systematic error in electrokinetic injection caused by induced (hydrodynamic) flow in sheathless capillary electrophoresis/electrospray have been characterized for an interface constructed from 5 pm i.d. capillary column(s) with a 2-5 pm i.d. electrospray tip(s).