Shape selectivity of stationary phases for the separation of isomeric hydrocarbons by capillary gas chromatography
✍ Scribed by Ladislav Soják; Ivan Ostrovský
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 522 KB
- Volume
- 446
- Category
- Article
- ISSN
- 1873-3778
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✦ Synopsis
The selectivity coefficients and retention ranges of isomeric hydrocarbons on various stationary phases were compared. The advantage of liquid crystals, used as shape-selective stationary phases in capillary gas chromatography for the separation of structural and geometric isomers and diastereoisomers of hydrocarbons, is demonstrated.
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New chiral stationary phases of polydimethylsiloxane anchored with (S)-(À)-t-leucine derivatives were provided for use in enantiomer separation of pharmaceuticals by capillary gas chromatography. Fifteen pharmaceuticals were separated into their enantiomeric pairs by converting them into pentafluoro
## Heptakis(2,3-di-O-methyl-6-O-tert-butyldimethylsilyl)-~-cyclodextrin This chral stationary phase was described by A Dietrich,
Heptakis(2,3-di-O-acetyl-6-O-tert-butyldimethylsilyl)-~-cyclodextrin This chiral stationary phase was described by A Dietrich, B Maas, V Karl, P Kreis, D Lehmann, B Weber, and A Mosandl. HRC 15 (1992) 176 -179 Column D: 30m x 0.25 mm i.d. Fused Silica, df = 0.25 mm, 42 % cyclodextrin in OV-1701-vi C