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Shape-selective olefin epoxidation catalyzed by manganese picnic basket porphyrins

โœ Scribed by Collman, James P.; Zhang, Xumu; Hembre, Robert T.; Brauman, John I.


Book ID
121282035
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
304 KB
Volume
112
Category
Article
ISSN
0002-7863

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Epoxidation of olefins catalyzed by mang
โœ Zhen Li; Chun-Gu Xia ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 84 KB

The epoxidation of several alkenes catalyzed by (meso-tetrakis(pentafluorophenyl)porphinato) manganese(III) chloride (MnTFPPCl) was carried out in a 3:1 [bmim]PF 6 ionic liquid/CH 2 Cl 2 mixed solvent. The conversion and the yield of epoxide are excellent. It was also found that [bis(acetoxy)iodo]be