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Epoxidation of olefins catalyzed by manganese(III) porphyrin in a room temperature ionic liquid

✍ Scribed by Zhen Li; Chun-Gu Xia

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 84 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00190-4

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✦ Synopsis

The epoxidation of several alkenes catalyzed by (meso-tetrakis(pentafluorophenyl)porphinato) manganese(III) chloride (MnTFPPCl) was carried out in a 3:1 [bmim]PF 6 ionic liquid/CH 2 Cl 2 mixed solvent. The conversion and the yield of epoxide are excellent. It was also found that [bis(acetoxy)iodo]benzene [PhI(OAc) 2 ] is a more efficient oxidant than PhIO. The catalyst in the ionic liquids can be recycled for several runs without substantial diminution in the catalytic activity.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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