The correlation between paramagnetism and the shnkc-up wlcllites in the X-ray photoelcclron spectra of the 3d transition-metal compounds is examined and explained in wrms OP modified sehxtion rules governing ~hc shake-up Volume 14. number I CIIEhllCAL PHYSICS LETTERS
Shake-up satellites in x-ray photoelectron (ESCA) spectra of 5f0 Th(IV) compounds
โ Scribed by G.M. Bancroft; T.K. Sham; J.L. Esquivel; S. Larsson
- Book ID
- 107731532
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 498 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Exatiination of the various &r&ions liable to contribute to stetite profiles in X-ray photoelectron spectra of 3d-transition metal compounds is intended Lo show the inadequacy of the monopble selection rule which has been wed to account for the app.zrent conelztion between satellite!; and pammagneti
Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This
The X-ray photoelectron spcctn of the Na and Mg atoms xc thcoreticdlg studied wlrh an ab mitlo Cl cdcul~~ion. Ills shtikcup cnerw and infcnsity ukulalcd for Na are m good qrecmunt with c\pcrimcnt, whereas .I slgnifiwnt disqrccment is found for hlg. The satelhte obscrwd (II 6.1 eV from the hlg Is pcf