Seven-membered ring synthesis based on arene olefin cycloadditions: The total synthesis of (±)-Rudmollin
✍ Scribed by Paul A Wender; Karl Fisher
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 274 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Seven-Membered Ring Synthesis Based On Arene Olefin Cycloadditions:
The Total Synthesis of (f)-Rudmollin1*2
📜 SIMILAR VOLUMES
An eight step synthesis of the iridoid isoiridomyrmecin is described, in which new methodology for the stereooontrolled elaboration of arene-olefin oycloadducts is delineated. The arene-olefin cycloadditionlr\* provides a general approach to polyquinane synthesis in which a tricyclo[3.3.0.02~\*lcct
## Abstract Highly substituted carbocyclic seven‐membered rings are frequently found in natural products and their synthesis represents a significant challenge to the synthetic chemist. Direct intramolecular cyclization of these systems often proves difficult and this fact has catalyzed the develop