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The Cycloaddition Strategy for the Synthesis of Natural Products Containing Carbocyclic Seven-Membered Rings

✍ Scribed by Merle A. Battiste; Phillip M. Pelphrey; Dennis L. Wright

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
261 KB
Volume
12
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

Highly substituted carbocyclic seven‐membered rings are frequently found in natural products and their synthesis represents a significant challenge to the synthetic chemist. Direct intramolecular cyclization of these systems often proves difficult and this fact has catalyzed the development of a variety of strategies based on a convergent intermolecular cycloaddition strategy. This concept article discusses the major cycloaddition approaches utilized to access these types of structures and primarily focuses on examples employed in the synthesis of natural products.

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