## Abstract Four new halogenated sesquiterpenes, 10‐bromo‐3‐chloro‐2,7‐epoxychamigr‐9‐en‐8__α__‐ol (**1**), 2,10__β__‐dibromochamigra‐2,7‐dien‐9__α__‐ol (**2**), (9__S__)‐2‐bromo‐3‐chloro‐6,9‐epoxybisabola‐7(14),10‐diene (**3**), and (9__R__)‐2‐bromo‐3‐chloro‐6,9‐epoxybisabola‐7(14),10‐diene (**4**
Sesquiterpenes and Other Metabolites from the Marine Red Alga Laurencia composita (Rhodomelaceae)
✍ Scribed by Nai-Yun Ji; Xiao-Ming Li; Bin-Gui Wang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- German
- Weight
- 165 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Two new halogenated sesquiterpenes, (8__β__)‐10‐bromo‐3‐chloro‐2,7‐epoxychamigr‐9‐en‐8‐ol (1) and 2‐bromo‐3‐chlorobisabola‐7(14),11‐diene‐6,10‐diol (3), and one new phytol‐derived diterpene, 2,3‐epoxyphytyl acetate (4), along with cis‐ and trans‐1‐methylcyclohexane‐1,4‐diol (5 and 6) which were isolated from a natural source for the first time but have been previously synthesized, were isolated from the marine red alga Laurencia composita and characterized. In addition, a known sesquiterpene, pacifenediol (2), and the known furanone derivative 7 were also identified. Their structures were established by NMR and mass spectroscopic methods.
📜 SIMILAR VOLUMES
## Abstract Three new polybrominated 1__H__‐indoles, compounds **1**–**3**, and three new aristolane sesquiterpenes, compounds **4**–**6**, were isolated from the marine red alga __Laurencia similis__, together with seven known natural products. Their structures were elucidated on the basis of deta
## Abstract Together with five known sesquiterpenes, EtOH extraction of __Laurencia saitoi__ yielded four new compounds, including three sesquiterpenes and one norsesquiterpene derivative. Their structures and relative configurations were elucidated by spectroscopic methods, including 1D‐ and 2D‐NM
## Abstract Two new brominated diterpenes, namely, laurendecumtriol (**1**) and 11‐__O__‐deacetylpinnaterpene C (**2**), one new polybromoindole, 2,3,4,6‐tetrabromo‐1‐methyl‐1__H__‐indole (**7**), and six known natural products were isolated and identified from the marine red alga __Laurencia decum
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