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Sequence of Orbitals in Sulfones and Sulfodiimides

✍ Scribed by Dipl.-Chem. Bahman Solouki; Prof. Dr. Hans Bock; Prof. Dr. Rolf Appel


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
271 KB
Volume
11
Category
Article
ISSN
0044-8249

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Synthesis of vinylic and cyclic sulfones
✍ Albert Padwa; S.Shaun Murphree; Philip E. Yeske πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 253 KB

Radical attack on the double bond of 2,3-bis(phenylsulfonyl)-1 -propene leads to an intermediate sulfonyl stabilized radical. This species readily fragments to produce a new vinyl sulfone which can undergo further radical cyclization to give a six ring sulfone.