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Separation of Scattering and Absorption Contributions in UV/Visible Spectra of Resonant Systems

✍ Scribed by Micali, Norberto; Mallamace, Francesco; Castriciano, Mariangela; Romeo, Andrea; Monsú Scolaro, Luigi

Book ID
125809567
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
76 KB
Volume
73
Category
Article
ISSN
0003-2700

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Fluorescence and UV-visible absorption spectra of HPTS (8-hydroxy-1,3,6-pyrenetrisulphonic acid trisodium salt, pyranine) were measured in a variety of solvents. Fluorescence maxima (in kcal mol -1 ) can be correlated with the Kosower Z parameter (r = 0.901), the Dimroth-Reichardt E T (30) parameter