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Separation of optical isomers by ion-exchange chromatography using copper(II) ions as complex-forming agents

✍ Scribed by J. Gaál; J. Inczédy

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
364 KB
Volume
102
Category
Article
ISSN
1873-3778

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✦ Synopsis

On the basis of the differences between the stability constants of complexes of D-and L-aminodiols with copper ions, an ion-exchange chromatographic method using copper(I1) ions as complex-forming agents was developed for the quantitative separation of pairs of optical isomers. The stability constants of some complexes were determined. The distribution coefficients of two enantiomers were examined by static batch and elution methods. The optimal conditions of the separation and the composition of the eluent are discussed.

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