Isotachophoretic separation of Fe(II) and Fe(III) by using 1,10-phenanthroline as a complex-forming agent
✍ Scribed by Takeshi Hirokawa; Kazuhiro Nishimoto; Fumitaka Nishiyama
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 411 KB
- Volume
- 723
- Category
- Article
- ISSN
- 1873-3778
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## Abstract In order to monitor the progression of the synthesis and the separation of novel mixed‐ligand iron complexes containing 1,10‐phenanthroline, 1,10‐phenanthroline‐5,6‐dione, and NCS^−^ as ligands all products were mass analyzed by electrospray ionization ion trap MS/MS. The spectra of met
The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat