Separation of enantiomers by open capillary electrochromatography on polysiloxane-bonded permethyl-β-cyclodextrin
✍ Scribed by Volker Schurig; Sabine Mayer
- Book ID
- 117331079
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 316 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0165-022X
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Fused silica tubing (50 pm i d and 375 pm o.d., manufactured by Chrompack International, Middelburg, The Netherlands) was purged with hydrogen gas at 270 "C for 2 h. A capillary of 2.5 m in
## Abstract Immobilized polysiloxane‐anchored permethyl‐β‐cyclodextrin (Chirasil‐Dex) with a cyclodextrin content of approximately 30 % by weight, previously employed as a versatile chiral stationary phase for the separation of enantiomers by GC, has been used for the separation of enantiomers by c
## Enantiomer separation by capillary electrochromatography on a cyclodextrinmodified monolith A chiral monolithic stationary phase was prepared by packing a capillary with bare porous silica and sintering the silica bed at high temperature. The resulting silica monolith was polymer-coated with Ch
## Abstract Immobilized permethyl‐β‐cyclodextrin was used for enantiomer separation by capillary supercritical fluid chromatography and gas chromatography. The influences of pressure and temperature on chiral separation factors, α, and capacity factors, k, have been studied for four representative