Separation of C60 and C70 fullerenes on methoxyphenylpropyl bonded stationary phases in microcolumn liquid chromatography
โ Scribed by Kiyokatsu Jinno; Yoshihiro Saito; Yung-Lin Chen; Gary Luehr; Jim Archer; John C. Fetzer; Wilton R. Biggs
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 411 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1040-7685
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โฆ Synopsis
Abstract
Chromatographic separation of C~60~ and C~70~ fullerenes was performed with phenylpropyl and three different methoxyphenylpropyl bonded phases in microcolumn liquid chromatography. The results indicate that the 3,4โdimethoxyphenylpropyl phase possesses the best resolving power among the evaluated phases, producing a separation factor of 1.87 for C~70~ and C~60~ using nโhexane as the mobile phase. This observation could be explained by examining the energy minimized conformations of the bonded phases and their associative interactions with the fullerene molecules.
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