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Separation of C60 and C70 fullerenes on methoxyphenylpropyl bonded stationary phases in microcolumn liquid chromatography

โœ Scribed by Kiyokatsu Jinno; Yoshihiro Saito; Yung-Lin Chen; Gary Luehr; Jim Archer; John C. Fetzer; Wilton R. Biggs


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
411 KB
Volume
5
Category
Article
ISSN
1040-7685

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โœฆ Synopsis


Abstract

Chromatographic separation of C~60~ and C~70~ fullerenes was performed with phenylpropyl and three different methoxyphenylpropyl bonded phases in microcolumn liquid chromatography. The results indicate that the 3,4โ€dimethoxyphenylpropyl phase possesses the best resolving power among the evaluated phases, producing a separation factor of 1.87 for C~70~ and C~60~ using nโ€hexane as the mobile phase. This observation could be explained by examining the energy minimized conformations of the bonded phases and their associative interactions with the fullerene molecules.


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