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Separating solvation from molecular diffusion in polymers

✍ Scribed by Yossef A. Elabd; Timothy A. Barbari


Publisher
American Institute of Chemical Engineers
Year
2001
Tongue
English
Weight
173 KB
Volume
47
Category
Article
ISSN
0001-1541

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Two optically based, molecular probe techniques are employed to study relaxation and small-molecule translational diffusion in thin and ultrathin (thicknesses Γ΅ Γ‡200 nm) polymer films. Second harmonic generation (SHG) is used to study the reorientational dynamics of a nonlinear optical chromophore,