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Broadening of molecular-weight distribution in solid-state polymerization resulting from condensate diffusion

โœ Scribed by Michael D. Goodner; Stephen M. Gross; Joseph M. Desimone; George W. Roberts; Douglas J. Kiserow


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
270 KB
Volume
79
Category
Article
ISSN
0021-8995

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Calculating molecular weight distributio
โœ M. F. Cunningham; J. W. Ma ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 227 KB ๐Ÿ‘ 2 views

When highly reactive chain transfer agents with low water solubilities (e.g., long chain thiols) are used in emulsion polymerizations, transport of the chain transfer agent (CTA) from the monomer droplets to the polymer particles can become diffusion limited. Consequently, the concentration of CTA i