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Sensitized fluorescence of diatomic free radicals by Hg(63P0) metastables

✍ Scribed by A.C. Vikis; D.J. Le Roy

Book ID: 103010379
Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 420 KB
Volume: 21
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80024-7

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✦ Synopsis

hlercury 63Po metostobles were shown to sensltxze the emlsslon of a number of dlatomlc free radxais (HgH, HgCI, CN, OH, and NH) of photochemlcal Interest Evidence IS presented that the energy transfc: process IS a non-Francl-Condon one at least for HgCl and CN An Inverse rotational temperature dependence on nitrogen pressure was observed for the HgH(* n, ,2) U' = 0 state and attributed to near resonant rotational-rotatIona relaxation pracesscs tnvolvmg the zeroth and fust nbratlonal levels 1 Introductron

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