Semirigid model of the bending-rotational Hamiltonian in electron diffraction analysis of triatomic molecules
β Scribed by A. G. Gershikov; V. P. Spiridonov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1987
- Tongue
- English
- Weight
- 519 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A dynamIca: model IS developed appropnate for symmetric tnatomlc molecules with large-amphtude bendmg motion The total hamdtoruan IS separated mto rotation-bendmg and stretching parts The bendmg potent& LS approximated by a quartw-harmonic functmn. In the denvatmn of the mten=\*+\_J equntlon a curvl
The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment