Semiconductor photoinduced cycloreversion of the dimer of methyl 2-naphthoate
β Scribed by Chen-Ho Tung; Yun-Ming Ying
- Book ID
- 102097537
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 285 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0256-7660
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π SIMILAR VOLUMES
Molecular mechanics calculations were employed to study the inclusion of 2-methyl naphthoate in alpha- and beta-cyclodextrin in vacuo and in the presence of water as a solvent. The driving forces for complexation are dominated by nonbonded van der Waals host:guest interactions in both environments.
The title radicals dimerize to an a,p-dimer 1 and not to an cr,a-dimer 2 as previously 8) assumed. The structure of the dimers of t-benzhydryl radicals Ph2CR in general is strongly dependent on the bulkiness of the R group. Benzyl type radicals l can dimerize to form either a,n-dimers 2 or a,p-dime