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Semiconducting charge transfer complexes from [60]Fullerene-tetrathiafulvalene (C60-TTF) systems

✍ Scribed by Nazario Martín; Luis Sánchez; Carlos Seoane; Raquel Andreu; Javier Garín; Jesús Orduna


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
205 KB
Volume
37
Category
Article
ISSN
0040-4039

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In benzene solution, C60 and C7o interact weakly in the ground state with amines having favourable oxidation potentials. Picosecond time-resolved absorption measurements show that on photoexcilation, the weak complexes undergo charge separation to produce ion pairs which in turn undergo fast geminat