Self-Recombination Rate Constants for 2-Propanol and tert -Butyl alcohol Radicals in Water †
✍ Scribed by Mezyk, Stephen P.; Madden, Keith P.
- Book ID
- 121386860
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 102 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Absolute rate constants for the reactions of OH radicals with butyl ethyl ether ( k , ) , methyl tertbutyl ether (k2), ethyl tert-butyl ether ( k ] ) , tert-amyl methyl ether ( k 4 ) ) , and tert-butyl alcohol ( k 5 ) have been measured over the temperature range 230-372 K using a pulsed laser photo
## Abstract The decay of photochemically generated __tert__‐butyl radicals in methylcyclopentane solutions containing chloroform is studied by time‐resolved ESR spectroscopy. In the pure solvent it perfectly follows the second‐order rate law for radical self‐termination. Increasing chloroform conce
## Abstract A competitive method involving the direct measurement of radical concentrations by EPR spectroscopy has been used to show that in solution at 25°C the rate constants for the bimolecular self‐reactions of ethyl, isopropyl, __tert__‐butyl, cyclopentyl, and trichloromethyl are all approxim