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Self-Dissociating Tubules from Helical Stacking of Noncovalent Macrocycles

✍ Scribed by Ho-Joong Kim; Seong-Kyun Kang; Youn-Kyoung Lee; Prof. Chaok Seok; Jeong-Kyu Lee; Prof. Wang-Cheol Zin; Prof. Myongsoo Lee

Book ID: 102726255
Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 717 KB
Volume: 122
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201003779

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## Abstract The chiral tris‐monodentate imidazolinyl ligands **1 a**–**c** exhibit a strong tendency to form the discrete, helical [2+3] nanocages **3** ([**1**~2~**⋅2**~3~]) with tartaric acids **2**. Circular dichroism (CD) spectra and theoretical calculations reveal that supramolecular handednes