Helical self-assembled polymers from cooperative stacking of hydrogen-bonded pairs
✍ Scribed by Meijer, E. W.; Hirschberg, J. H. K. Ky; Brunsveld, Luc; Ramzi, Aissa; Vekemans, Jef A. J. M.; Sijbesma, Rint P.
- Book ID
- 109770753
- Publisher
- Nature Publishing Group
- Year
- 2000
- Tongue
- English
- Weight
- 440 KB
- Volume
- 407
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/35025027
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📜 SIMILAR VOLUMES
## Abstract The copper(II) complexes [Cu(H~2~L^1^)Cl~2~]~2~[CuCl~4~]·CH~3~CN·H~2~O (HL^1^ = __N__‐6‐(4‐hydroxyphenyl)‐2‐pyridylmethyl‐__N__,__N′__,__N′__‐trimethylethylenediamine), [Cu(HL^2^)Cl~2~] (HL^2^ = __N__‐4‐hydroxybenzylmethyl‐__N__,__N′__,__N′__‐trimethylethylenediamine)and [Cu~2~(μ‐L^3^)~
The H-b on d mediated self-assembly of the chiral &-symmetric bis-(2-amino-4-chloro-pyrimidines) 3 and 4 allows for the molecular recognition directed generation of helical superstructures. In the former case, unoccupied channel structures defined by the cylindrical interior of the derived supramole