Self-condensation of Terminal Acetylenic Ketones via Organozinc Species
β Scribed by Jun-Li GAO; Yong-Kang LIU; Song XUE
- Book ID
- 102097792
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 80 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0256-7660
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π SIMILAR VOLUMES
3-Butyn-2-one condenses with itself in the presence of 0.1 molar equiv of Dabco providing 80% yield of E-3-(1-buten-3-yn-2-oxy)-buten-2-one. Substitution at the acetylene terminus prevents the condensation. However, such ketones can be condensed with terminal acetylenic ketones to provide the cross
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