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Selenium-Ligated Palladium(II) Complexes as Highly Active Catalysts for Carbon−Carbon Coupling Reactions: The Heck Reaction

✍ Scribed by Yao, Qingwei; Kinney, Elizabeth P.; Zheng, Chong


Book ID
127194125
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
119 KB
Volume
6
Category
Article
ISSN
1523-7060

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A variety of palladium on activated carbon catalysts differing in Pd dispersion, Pd distribution, Pd oxidation state, and water content were tested in Heck reactions of aryl bromides with olefins. The optimization of the catalyst (structure ± activity relationship) and reaction conditions (temperatu